DYNAMIC PROPERTIES AND TIRE PERFORMANCES OF COMPOSITES FILLED WITH CARBON NANOTUBES

Abstract

ABSTRACT Carbon nanotubes (CNTs) have been widely studied in rubber goods and tire compounds to improve, for example, antistatic and thermal conductivity performances. CNTs were applied in passenger tire tread compounds to improve comprehensive tire performances, especially wet traction. High frequency dynamic properties of CNT-filled compounds were revealed for the first time. There was good correlation between compound dynamic properties and vehicle tire test results. The influence of CNTs on tire performances and their mechanisms was investigated and explained by the dynamic properties and master curve analysis in the frequency domain. Substituting 50 phr carbon black N234 by 20 phr CNTs could maintain hardness but increased static and dynamic moduli, which was beneficial for the tire handling, with 0.25 point improvement in the subjective testing. For the CNT-filled compounds, 1.5% traction improvement on a dry road and 6.5% traction improvement on a wet road can be explained successfully by the increased hysteresis loss (tan δ) and decreased storage modulus (G′) at high frequency domain (10 4 –10 8 Hz). It is implied by Williams–Landel–Ferry law calculation that a strong interaction between CNTs and rubber resulted in higher temperature dependence; however, the trade-off was a 7% higher tire rolling resistance coefficient and 33% worse wear resistance for the CNT tires. CNT-filled compounds were demonstrated to have superior handling and traction performances suitable for racing and sports car tires.