Highly Nitrogen‐Doped Porous Carbon Derived from Zeolitic Imidazolate Framework‐8 for CO<sub>2</sub> Capture

Xiancheng Ma; Liqing Li; Ruofei Chen; Chunhao Wang; Haoyang Li; Hailong Li

doi:10.1002/asia.201800548

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Highly Nitrogen‐Doped Porous Carbon Derived from Zeolitic Imidazolate Framework‐8 for CO₂ Capture

Xiancheng Ma Liqing Li Ruofei Chen Chunhao Wang Haoyang Li Hailong Li

Year: 2018 Journal: Chemistry - An Asian Journal Vol: 13 (16)Pages: 2069-2076 Publisher: Wiley

DOI: 10.1002/asia.201800548

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Abstract

Setting the trap: A nitrogen-doped porous carbon, with a nitrogen content of up to 25.52 % and specific surface area of 948 m² g^-1 , exhibits a superior CO₂ uptake of 3.7 mmol g^-1 at 25 °C and 1 bar. Experimental and theoretical results indicate that the nitrogen-containing functional groups enhance CO₂ uptake through electrostatic, Lewis acid-base, and hydrogen-bonding interactions.

Keywords:

Zeolitic imidazolate framework Nitrogen Carbon fibers Chemical engineering Porosity Hydrogen Chemistry Doping Computer science Nanotechnology Materials science Adsorption Organic chemistry Metal-organic framework Engineering Algorithm Optoelectronics

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Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Covalent Organic Framework Applications

Physical Sciences → Materials Science → Materials Chemistry

CO2 Reduction Techniques and Catalysts

Physical Sciences → Energy → Renewable Energy, Sustainability and the Environment

Highly Nitrogen‐Doped Porous Carbon Derived from Zeolitic Imidazolate Framework‐8 for CO₂ Capture

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