Preparation of Dual-Emitting Ln@UiO-66-Hybrid Films via Electrophoretic Deposition for Ratiometric Temperature Sensing

Abstract

Engineering novel dual-emitting metal-organic frameworks (MOFs) with wide emission ranges for application as ratiometric temperature sensors is still a challenge. In this paper, two novel dual-emitting MOFs with intergrated lanthanide metals and luminescent ligand in a UiO-66-type structure, named Ln@UiO-66-Hybrid, were prepared via the combination of postsynthetic modification and postsynthetic exchange methods. Subsequently, the as-synthesized MOFs were deposited onto fluorine tin oxide substrates through electrophoretic deposition by taking advantage of the charges from the unmodified carboxylic groups of the MOFs. The as-prepared Tb@UiO-66-Hybrid and Eu@UiO-66-Hybrid films were applied to detect temperature changes. The resulting Tb@UiO-66-Hybrid film exhibited good temperature-sensing properties with a relative sensitivity of up to 2.76% K^-1 in the temperature range of 303-353 K. In addition, the Eu@UiO-66-Hybrid film showed excellent temperature-sensing performance based on the energy transfer between the luminescent ligand (H₂NDC) and europium ions with a relative sensitivity of up to 4.26% K^-1 in the temperature range of 303-403 K.