Selective Palladium-Catalyzed Oxidation of Glycerol to Dihydroxyacetone

Andreas J. Wagner Contributor Paul Knochel; D. M. Pearson; R. M. Waymouth

doi:10.1055/s-0030-1259415

ScienceGate Book Chapters

JOURNAL ARTICLE

Selective Palladium-Catalyzed Oxidation of Glycerol to Dihydroxyacetone

Andreas J. Wagner Contributor Paul Knochel D. M. Pearson R. M. Waymouth

Year: 2011 Journal: Synfacts Vol: 2011 (03)Pages: 0308-0308 Publisher: Georg Thieme Verlag

DOI: 10.1055/s-0030-1259415

Get Full-Text PDF Get Analytical Report

Abstract

A dimeric phenanthroline-based palladium acetate complex catalyzes the chemoselective oxidative transformation of glycerol into dihydroxyacetone. Both benzoquinone and air are effective oxidants and the reaction proceeds readily on a 10 mmol scale in wet acetonitrile or DMSO as solvents.

Keywords:

Dihydroxyacetone Chemistry Palladium Glycerol Catalysis Acetonitrile Organic chemistry Benzoquinone Medicinal chemistry

Metrics

Cited By

0.00

FWCI (Field Weighted Citation Impact)

Refs

0.26

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Topics

Oxidative Organic Chemistry Reactions

Physical Sciences → Chemistry → Organic Chemistry

Mesoporous Materials and Catalysis

Physical Sciences → Materials Science → Materials Chemistry

Chemical Synthesis and Reactions

Physical Sciences → Chemistry → Organic Chemistry

Selective Palladium-Catalyzed Oxidation of Glycerol to Dihydroxyacetone

Abstract

Metrics

Topics

Related Documents

Selective Catalytic Oxidation of Glycerol to Dihydroxyacetone

Selective Catalytic Oxidation of Glycerol to Dihydroxyacetone

The MechanisticStudy of Palladium-Catalyzed Conversionof Glycerol to Dihydroxyacetone

The Mechanistic Study of Palladium-Catalyzed Conversion of Glycerol to Dihydroxyacetone

Selective\nElectro-Oxidation of Glycerol to Dihydroxyacetone\nby PtAg Skeletons