A Highly Active and Reusable Heterogeneous Ruthenium Catalyst
Abstract
The Grubbs-type Ru carbene complex anchored on the mesoporous silica material (SBA-15) was prepared and applied to the olefin metathesis reaction. Of the immobilized ligands, the mesoporous silica-supported catalyst 1-SBA-15 was found to give high catalytic activity. The ring-closing metathesis reaction of diallylmalonate took place in the presence of 1-SBA-15 to give cyclopent-3-ene-1,1-dicarboxylic acid diethyl ester in 98% yield. The catalyst 1-SBA-15 was reused five times without any loss of reactivity (see scheme). Under this reaction conditions, no Ru leaching was observed (ICP analysis). Five substrates were examined (82-100% yield).
Metrics
Topics
Related Documents
A Highly Active and Reusable Heterogeneous Ruthenium Catalyst for Olefin Metathesis
Nanozirconia supported ruthenium(0) nanoparticles: Highly active and reusable catalyst in hydrolytic dehydrogenation of ammonia borane
Yalçın TonbulSerdar AkbayrakSaim Özkâr
Iron-Containing Mesoporous Aluminosilicate: A Highly Active and Reusable Heterogeneous Catalyst for Hydroarylation of Styrenes
Satyajit Haldar (2270047)Subratanath Koner (1985500)
Thermally Reduced Ruthenium Nanoparticles as a Highly Active Heterogeneous Catalyst for Hydrogenation of Monoaromatics
Fabing SuLu LvFang Yin LeeTao LiuAndrew I. CooperXin Zhao
Iron-Containing Mesoporous Aluminosilicate: A Highly Active and Reusable Heterogeneous Catalyst for Hydroarylation of Styrenes
Satyajit HaldarSubratanath Koner