A stable porphyrinic metal–organic framework pore-functionalized by high-density carboxylic groups for proton conduction

Hao Wu; Fan Yang; Xiu‐Liang Lv; Bin Wang; Yong‐Zheng Zhang; Minjian Zhao; Jian‐Rong Li

doi:10.1039/c7ta03917d

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A stable porphyrinic metal–organic framework pore-functionalized by high-density carboxylic groups for proton conduction

Hao Wu Fan Yang Xiu‐Liang Lv Bin Wang Yong‐Zheng Zhang Minjian Zhao Jian‐Rong Li

Year: 2017 Journal: Journal of Materials Chemistry A Vol: 5 (28)Pages: 14525-14529 Publisher: Royal Society of Chemistry

DOI: 10.1039/c7ta03917d

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Abstract

A highly stable porphyrinic MOF with free-carboxylic group functionalized pore surfaces exhibits a high proton conductivity of 3.9 × 10⁻² S cm⁻¹ at 80 °C and 97% RH, which is comparable to most of the reported proton conductive MOFs.

Keywords:

Proton Metal-organic framework Conductivity Chemistry Metal Thermal conduction Electrical conductor Carboxylic acid Polymer chemistry Materials science Physical chemistry Organic chemistry Composite material Physics Adsorption Nuclear physics

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Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Fuel Cells and Related Materials

Physical Sciences → Engineering → Electrical and Electronic Engineering

Covalent Organic Framework Applications

Physical Sciences → Materials Science → Materials Chemistry

A stable porphyrinic metal–organic framework pore-functionalized by high-density carboxylic groups for proton conduction

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