Activation of peroxymonosulfate with magnetic and recyclable Fe₃O₄@C/MnCo₂O₄ nanocomposites for the decolorization of Acid Orange II

Abstract

Abstract BACKGROUND Synthetic dyes are present in the wastewater from many industrial processes and they cause serious problems to human and aquatic life. The development of a novel and effective peroxymonosulfate ( PMS ) activator is proposed to eliminate dyes pollution. A new magnetic nanocomposite, Fe 3 O 4 @C/ MnCo 2 O 4 , was prepared and characterized. The activity of Fe 3 O 4 @C/ MnCo 2 O 4 as heterogeneous catalyst for PMS activation was evaluated by the decolorization of Acid Orange II ( AO II ). RESULTS With a ‘ Fe 3 O 4 @C/ MnCo 2 O 4 + PMS ’ system, the dye solution could be nearly completely decolorized in about 25 min over a wide pH range ( pH 4.1−8.1), and 98% removal could be achieved in 15 min without pH adjustment ( pH = 6.38). The influence of solution pH , dosage of catalyst and PMS , reaction temperature, and PMS activation mechanism were studied. It was found that sulfate radicals were the primary species responsible for the oxidation of AO II . The catalyst was magnetically separable and displayed good stability and reusability, giving six cycles of use without deterioration in its performance. CONCLUSION This study demonstrated the simple recycling and high activity of Fe 3 O 4 @C/ MnCo 2 O 4 composite in PMS activation for the decolorization of AO II solution. It provides a promising way for the decontamination of organic pollutants. © 2016 Society of Chemical Industry