Ag(<scp>i</scp>)-based high-energy metal organic frameworks (HE-MOFs) incorporating coordinated moieties in channels: synthesis, structure and physicochemical properties

Xiaxia Song; Sheng Zhang; Guowei Zhao; Wendou Zhang; Dongpo Chen; Qi Yang; Qing Wei; Gang Xie; De‐Suo Yang; Sanping Chen; Shengli Gao

doi:10.1039/c6ra21132a

JOURNAL ARTICLE

Ag(i)-based high-energy metal organic frameworks (HE-MOFs) incorporating coordinated moieties in channels: synthesis, structure and physicochemical properties

Xiaxia Song Sheng Zhang Guowei Zhao Wendou Zhang Dongpo Chen Qi Yang Qing Wei Gang Xie De‐Suo Yang Sanping Chen Shengli Gao

Year: 2016 Journal: RSC Advances Vol: 6 (96)Pages: 93231-93237 Publisher: Royal Society of Chemistry

DOI: 10.1039/c6ra21132a

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Abstract

A new Ag(i)-based HE-MOFs exhibited a compact 3D structure with channels containing coordinated NO₃⁻ and CH₃COO⁻ ions. The superior density, thermostability, insensitiveness and detonation properties indicated it can be used as potential explosive.

Keywords:

Thermostability Detonation Explosive material Chemistry Metal-organic framework Energy density Metal Ion Crystallography Physical chemistry Organic chemistry Physics Adsorption

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Energetic Materials and Combustion

Physical Sciences → Engineering → Mechanics of Materials

Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Thermal and Kinetic Analysis

Physical Sciences → Materials Science → Materials Chemistry

Ag(i)-based high-energy metal organic frameworks (HE-MOFs) incorporating coordinated moieties in channels: synthesis, structure and physicochemical properties

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