Carbon Quantum Dots sensitized Vertical WO ₃ Nanoplates with Enhanced Photoelectrochemical Properties

Abstract

Abstract WO 3 nanoplates (WO 3 NP) sensitizing with carbon quantum dots (CQDs) photoanode was successfully fabricated by simple hydrothermal and immersing process under mild temperature. The as‐prepared composites were characterized by X‐ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high‐resolution TEM, Raman spectrometer and ultraviolet visible spectrometry (UV‐vis). The WO 3 photoanode after CQDs loading exhibited an enhanced photocurrent density of ∼1.18 mA cm −2 at 1.23 V vs RHE, compared to 0.96 mA cm −2 of pristine WO 3 under simulated solar light illumination. Moreover, the modified WO 3 nanoplates with CQDs show a superior ability to capture visible light, resulting in more than 1.6 folds of photocurrent density enhancement. Meanwhile, a lower onset potential can be obtained after sensitizing, which is caused by the change of band energy positions. Notably, this efficient sensitization of CQDs could introduce a promising route to improve the light harvesting and efficiency of photoelectrochemical properties for WO 3 based photoanode.