(NH4)4Na2[Mo2VIV2VV6O28].10H2O

Yan Xu; Jian-Wen Xu; Guo‐Yu Yang; Yan Xing; Yuan Lin; Heling Jia

doi:10.1107/s0108270198008853

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(NH₄)₄Na₂[Mo₂V^IV₂V^V₆O₂₈].10H₂O

Yan Xu Jian-Wen Xu Guo‐Yu Yang Yan Xing Yuan Lin Heling Jia

Year: 1998 Journal: Acta Crystallographica Section C Crystal Structure Communications Vol: 54 (12)Pages: 1733-1735 Publisher: Wiley

DOI: 10.1107/s0108270198008853

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Abstract

The title compound, tetraammonium disodium octacosaoxo(dimolybdenumoctavanadium)ate decahydrate, is a mixed V/Mo salt which has a well known decavanadate structure. The centrosymmetric polyanion consists of eight (V/Mo)O6 and two VO6 edge-sharing distorted octahedra. Each of the two Na+ cations is surrounded by six water molecules in a distorted octahedron. The V—O and (V/Mo)—O distances are between 1.571 (6) and 2.432 (5) Å.

Keywords:

Vanadate Chemistry Vanadium Crystallography Hydrate Ammonium Inorganic chemistry

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Polyoxometalates: Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Vanadium and Halogenation Chemistry

Physical Sciences → Chemistry → Inorganic Chemistry

(NH₄)₄Na₂[Mo₂V^IV₂V^V₆O₂₈].10H₂O

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