Room temperature CO sensing by polyaniline/Co₃O₄ nanocomposite

Abstract

ABSTRACT Polyaniline/cobalt oxide (PANI/Co 3 O 4 ) nanocomposites have been investigated for their sensitivity towards carbon monoxide (CO) gas at room temperature. The Co 3 O 4 nanoparticles were prepared by ultrasound assisted coprecipitation method and then incorporated into the PANI matrix. Fourier transform infrared spectroscopy and ultraviolet–visible spectroscopy, powder X‐ray diffraction, and field emission scanning electron microscopy have been used to characterize the nanomaterials. The PANI/Co 3 O 4 nanocomposite sensors were found to be highly selective to CO gas at room temperature. A significantly high response of 0.81 has been obtained for 75 ppm CO concentration with a response time of 40 s. Based on the observations of the sensing study, a mechanism for CO sensing by the nanocomposite has been proposed. Influence of humidity on the sensor response towards CO has also been studied and the results presented. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133 , 44115.