ChemInform Abstract: Unexpected Dissociative Kinetics for CO Exchange in the 17‐Electron Complexes Carbonylbis(η5‐pentadienyl)vanadium(II), Carbonyl(η5‐cyclopentadienyl)(η5‐pentadienyl)vanadium(II), and Carbonyl(η5‐cyclopentadienyl)(η5‐2,4‐dimethylpentadienyl)vanadium(II).

Ruth M. Kowaleski; Fred Basolo; William C. Trogler; Richard D. Ernst

doi:10.1002/chin.198705271

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ChemInform Abstract: Unexpected Dissociative Kinetics for CO Exchange in the 17‐Electron Complexes Carbonylbis(η5‐pentadienyl)vanadium(II), Carbonyl(η5‐cyclopentadienyl)(η5‐pentadienyl)vanadium(II), and Carbonyl(η5‐cyclopentadienyl)(η5‐2,4‐dimethylpentadienyl)vanadium(II).

Ruth M. Kowaleski Fred Basolo William C. Trogler Richard D. Ernst

Year: 1987 Journal: ChemInform Vol: 18 (5) Publisher: Wiley

DOI: 10.1002/chin.198705271

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Abstract

Abstract The values for the rate constants for the CO exchange process for the title complexes (I) and (II) are determined and compared with the known data for the complexes (III).

Keywords:

Chemistry Cyclopentadienyl complex Vanadium Metal carbonyl Kinetics Medicinal chemistry Reaction rate constant Inorganic chemistry Organic chemistry Catalysis Metal

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ChemInform Abstract: Unexpected Dissociative Kinetics for CO Exchange in the 17‐Electron Complexes Carbonylbis(η5‐pentadienyl)vanadium(II), Carbonyl(η5‐cyclopentadienyl)(η5‐pentadienyl)vanadium(II), and Carbonyl(η5‐cyclopentadienyl)(η5‐2,4‐dimethylpentadienyl)vanadium(II).

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