ChemInform Abstract: 1,2,4‐TRIAZOLIUM YLIDES. II. REGIOSELECTIVITY OF 3 + 2 DIPOLAR CYCLOADDITION OF TRIAZOLIUM PHENACYLIDES TO ASYMMETRIC DIPOLAROPHILES

M. Petrovanu; Camelia Elena Luchian; Georgiana Surpateanu; Virgil Bărboiu

doi:10.1002/chin.197952199

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ChemInform Abstract: 1,2,4‐TRIAZOLIUM YLIDES. II. REGIOSELECTIVITY OF 3 + 2 DIPOLAR CYCLOADDITION OF TRIAZOLIUM PHENACYLIDES TO ASYMMETRIC DIPOLAROPHILES

M. Petrovanu Camelia Elena Luchian Georgiana Surpateanu Virgil Bărboiu

Year: 1979 Journal: Chemischer Informationsdienst Vol: 10 (52) Publisher: Wiley

DOI: 10.1002/chin.197952199

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Abstract

Abstract Die aus dem Phenyltriazol (I) und den Phenacylbromiden (II) gebildeten Triazoliumbromide (III) werden mit Triethylamin zu den Yliden (IV) umgesetzt, die in situ an Acrylnitiil und Acrylsäuremethylester (V) cycloaddiert werden.

Keywords:

Regioselectivity Cycloaddition 1,3-Dipolar cycloaddition Chemistry In situ Dipole Stereochemistry Medicinal chemistry Organic chemistry Catalysis

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Synthesis and biological activity

Physical Sciences → Chemistry → Organic Chemistry

Synthesis and Characterization of Heterocyclic Compounds

Physical Sciences → Chemistry → Organic Chemistry

Microwave-Assisted Synthesis and Applications

Physical Sciences → Chemistry → Organic Chemistry

ChemInform Abstract: 1,2,4‐TRIAZOLIUM YLIDES. II. REGIOSELECTIVITY OF 3 + 2 DIPOLAR CYCLOADDITION OF TRIAZOLIUM PHENACYLIDES TO ASYMMETRIC DIPOLAROPHILES

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