JOURNAL ARTICLE

4-Bromo-N2,N2,N6,N6-tetraethylpyridine-2,6-dicarboxamide

Daniel T. de LillAna de Bettencourt‐Dias

Year: 2010 Journal:   Acta Crystallographica Section E Structure Reports Online Vol: 66 (8)Pages: o2124-o2124   Publisher: International Union of Crystallography

Abstract

The title compound, C(15)H(22)BrN(3)O(2), consists of a pyridine ring with a bromine atom in the para position and two diethyl-amide groups in the ortho positions of the ring. Despite the positions of the three substituents on the pyridine ring, the mol-ecule does not exhibit either local or crystallographic twofold symmetry as the two diethyl-amido units exhibit significantly different N(py)-C-C-N(am) torsion angles of 46.3 (4) and 62.7 (4)° (py is pyridine and am is amine). Inter-molecular C-H⋯O inter-actions support the packing.

Keywords:
Pyridine Ring (chemistry) Chemistry Bromine Amide Crystallography Amine gas treating Stereochemistry Medicinal chemistry Organic chemistry

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Citation History

Topics

Crystal structures of chemical compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry
Lanthanide and Transition Metal Complexes
Physical Sciences →  Materials Science →  Materials Chemistry
Metal-Organic Frameworks: Synthesis and Applications
Physical Sciences →  Chemistry →  Inorganic Chemistry

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