JOURNAL ARTICLE

ChemInform Abstract: REACTIONS OF COORDINATED LIGANDS. 22. REACTIVITY OF BIS(ETHYLENE)(η5‐INDENYL)RHODIUM IN DISPLACEMENT REACTIONS WITH OLEFINS, DIENES, AND ACETYLENES; STRUCTURE OF η5‐INDENYL(1‐2:3‐4‐η4‐(6‐ENDO‐PROP‐2‐ENYL‐1,2,3,4‐TETRAKIS(TRIFLUOROMET# HYL)CYCLOHEXA‐1,3‐DIENE))RHODIUM

Abstract

Abstract Im Gegensatz zu dem η 5 ‐Cyclopentadienyl‐Analogen werden in dem η 5 ‐Indenyl‐Komplex (II), dargestellt aus Chloro‐bis‐[ethylen]‐Rh‐Dimerem und Indenyl‐K, beide Ethylen‐Liganden durch Isopren, trans‐Pentadien, trans,trans‐Hexadien, Cyclooctatetraen, Methylencyclopropan oder Acrylnitril unter Bildung der Derivate (I) bzw. (III) substituiert.

Keywords:
Chemistry Cyclopentadienyl complex Rhodium Ethylene Reactivity (psychology) Medicinal chemistry Stereochemistry Catalysis Organic chemistry

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Topics

Organometallic Complex Synthesis and Catalysis
Physical Sciences →  Chemistry →  Organic Chemistry
Coordination Chemistry and Organometallics
Physical Sciences →  Chemistry →  Organic Chemistry
Asymmetric Hydrogenation and Catalysis
Physical Sciences →  Chemistry →  Inorganic Chemistry

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