JOURNAL ARTICLE

Excess Molar Volumes of Ternary Mixtures of {x1CH3CH2COOCH2CH3 + x2CH3(CH2)4CH3 + (1 − x1x2)CH3(CH2)6OH or CH3(CH2)7OH} at the Temperature of 298.15 K

Carlos JiménezC. FranjoLuisa SegadeJ.L. LegidoM. I. Paz Andrade

Year: 1997 Journal:   Journal of Chemical & Engineering Data Vol: 42 (2)Pages: 262-265   Publisher: American Chemical Society

Abstract

Excess molar volumes at the temperature 298.15 K were measured for the ternary systems (x1ethyl propanoate + x2hexane + (1 − x1 − x2)heptan-1-ol or (1 − x1 − x2)octan-1-ol} and for binary mixtures {x1ethyl propanoate + (1 − x1)n-hexane}, {x1ethyl propanoate + (1 − x1)heptan-1-ol}, {x1n-hexane + (1 − x1)heptan-1-ol}, {x1ethyl propanoate + (1 − x1)octan-1-ol}, and {x1n-hexane + (1 − x1)octan-1-ol}. Excess molar volumes were determined using a densimeter Anton Paar DMA 60/602. The experimental values were compared with the results obtained with some empirical methods for the estimation of ternary properties from binary results.

Keywords:
Chemistry Ternary operation Hexane Molar Ternary numeral system Molar volume Binary system Analytical Chemistry (journal) Binary number Thermodynamics Chromatography Organic chemistry Phase (matter)

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Topics

Thermodynamic properties of mixtures
Physical Sciences →  Chemical Engineering →  Fluid Flow and Transfer Processes
Phase Equilibria and Thermodynamics
Physical Sciences →  Engineering →  Biomedical Engineering
Chemical Thermodynamics and Molecular Structure
Physical Sciences →  Chemistry →  Organic Chemistry
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