Diaquabis[5-(5-carboxy-2-pyridyl)tetrazolato-κ²N¹,N⁵]cadmium(II) dihydrate

Abstract

In the title complex, [Cd(C(7)H(4)N(5)O(2))(2)(H(2)O)(2)]·2H(2)O, the water-coordinated Cd(II) atom ( symmetry) is coordinated by four N atoms from two symmetry-related 3-carboxy-pyidyl-6-tetra-zolato ligands, forming a distorted octa-hedral complex. The uncoordinated water mol-ecules connect the mononuclear units into a layer structure through O-H⋯N and O-H⋯O hydrogen bonds; similar hydrogen bonds between coordinated water mol-ecules and anionic groups result in a three-dimensional structure.