JOURNAL ARTICLE
ChemInform Abstract: TRANSITION METAL‐CARBYNE COMPLEXES. XXXXI. OPTICAL ACTIVITY OF TRANSITION METAL‐CARBYNE COMPLEXES
S. FontanaOlli OramaE. O. FISCHERUlrich SchubertF. R. KREISSL
Year: 1978 Journal: Chemischer Informationsdienst Vol: 9 (32) Publisher: Wiley
Abstract
Abstract Chrom‐ und Wolfram‐hexacarbonyl (I) reagieren mit optisch aktivem Menthyllithium (II) und Trimethyloxoniumfluoroborat (III) zu den Methoxycarben‐ Komplexen (IV), aus denen durch Umsetzung mit Aluminiumbromid die optisch aktiven Carbinkomplexe (V) erhalten werden.
Keywords:
Carbyne Transition metal Metal Chemistry Polymer chemistry Stereochemistry Organic chemistry Catalysis
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Topics
Synthesis and characterization of novel inorganic/organometallic compounds
Physical Sciences → Chemistry → Inorganic Chemistry
Inorganic Fluorides and Related Compounds
Physical Sciences → Chemistry → Inorganic Chemistry
Catalysis and Oxidation Reactions
Physical Sciences → Chemical Engineering → Catalysis
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