JOURNAL ARTICLE
Preparation and Characterization of (C6H5CH2CH2NH3)4BiI7 · H2O, (C6H5CH2CH2NH3)3BiBr6 and (C6H5CH2CH2NH3)3BiCl6
G. C. PapavassiliouIoannis KoutselasAris TerzisCatherine P. Raptopoulou
Year: 1995 Journal: Zeitschrift für Naturforschung B Vol: 50 (10)Pages: 1566-1569 Publisher: De Gruyter
Abstract
The title compounds were prepared and characterized analytically, structurally, and spectroscopically. They contain isolated BiX 6 (X = I. Br, Cl) anions. Their optical absorption spectra show excitonic bands in the UV-visible spectral region. These bands occur at higher energies than the corresponding bands of R 3 M 2 X 9 (R = Me m NH 4-m ; m = 1,2, 3, 4).
Keywords:
Characterization (materials science) Absorption spectroscopy Spectral line Chemistry Absorption (acoustics) Analytical Chemistry (journal) Crystallography Physics Optics
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Topics
Crystal structures of chemical compounds
Physical Sciences → Chemistry → Inorganic Chemistry
Synthesis and characterization of novel inorganic/organometallic compounds
Physical Sciences → Chemistry → Inorganic Chemistry
Solid-state spectroscopy and crystallography
Physical Sciences → Materials Science → Materials Chemistry
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