有机阳离子-无机多阴离子复合物: 高分子体系中的组装及其自组装

Abstract

Organic cation-encapsulated inorganic polyoxometalate polyanion supramolecular complexes exhibiting defined chemical composition and amphiphilic core-shell structure, which lead to tunable and synergetic structure and function of organic and inorganic components were summarized in this review. The self-assembly and polymer functional composite materials based on this type of complexes as pre-organization units were introduced to reveal a novel type of building block system for various supramolecular assemblies. The strategies to achieve the assembly and functionality in structure stable and well processable matrixes based on the pre-organization complexes were thought the key content of research in this field. It was believed highly important to assemble and functionalize the complexes in a well dispersed way in polymer materials. This review summarized the development of polymer nano-composite materials and assembly in solution based on the supramolecular complexes, and a perspective was anticipated.