JOURNAL ARTICLE

Poly[μ3-aqua-aqua(μ3-3,5-dinitrobenzoato-κO1:O3:O5)caesium]

Graham Smith

Year: 2012 Journal:   Acta Crystallographica Section E Structure Reports Online Vol: 68 (10)Pages: m1241-m1242   Publisher: International Union of Crystallography

Abstract

In the structure of the title complex, [Cs(C(7)H(3)N(2)O(6))(H(2)O)(2)](n), the Cs salt of 3,5-dinitro-benzoic acid, the metal complex centres have have irregular CsO(8) coordination, comprising two water mol-ecules (one triply bridging and the other monodentate) and four O-atom donors from two nitro groups and one bridging carboxyl-ate O-atom donor from the ligand. Intra-unit O-H⋯O hydrogen-bonding inter-actions involving both water mol-ecules are observed in the three-dimensional polymeric complex structure.

Keywords:
Caesium Chemistry Physics Crystallography Nuclear physics

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Citation History

Topics

Crystal structures of chemical compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry
Metal-Organic Frameworks: Synthesis and Applications
Physical Sciences →  Chemistry →  Inorganic Chemistry
Metal complexes synthesis and properties
Health Sciences →  Medicine →  Oncology

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