A practical approach for regioselective mono-nitration of phenols under mild conditions

Ling‐Yan Chen; Tao Liu; Xiaokun Zhou; Zhihua Sun

doi:10.3998/ark.5550190.p008.587

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JOURNAL ARTICLE

A practical approach for regioselective mono-nitration of phenols under mild conditions

Ling‐Yan Chen Tao Liu Xiaokun Zhou Zhihua Sun

Year: 2014 Journal: ARKIVOC Vol: 2014 (5)Pages: 64-71 Publisher: ARKAT USA, Inc.

DOI: 10.3998/ark.5550190.p008.587

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Abstract

Cu(NO 3 ) 2 .3H 2 O was demonstrated to be an efficient, regioselective and inexpensive nitrating reagent for the synthesis of mono-nitro substituted phenolic compounds.12 examples of different phenols were examined.Good yields (67-90%) have been achieved.

Keywords:

Nitration Regioselectivity Chemistry Phenols Organic chemistry Combinatorial chemistry Computational chemistry Catalysis

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Chemical Synthesis and Reactions

Physical Sciences → Chemistry → Organic Chemistry

Oxidative Organic Chemistry Reactions

Physical Sciences → Chemistry → Organic Chemistry

Inorganic and Organometallic Chemistry

Physical Sciences → Chemistry → Organic Chemistry

A practical approach for regioselective mono-nitration of phenols under mild conditions

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