Sol-Gel Preparation and Third-Order Optical Nonlinearity of Amorphous Bi&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;-TiO&lt;sub&gt;2&lt;/sub&gt; and Nb&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;5&lt;/sub&gt;-TiO&lt;sub&gt;2&lt;/sub&gt; Films

Hiroyuki Nasu; Motohiko Sato; Jun Matsuoka; Kanichi Kamiya

doi:10.2109/jcersj.104.777

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Sol-Gel Preparation and Third-Order Optical Nonlinearity of Amorphous Bi2O3-TiO2 and Nb2O5-TiO2 Films

Hiroyuki Nasu Motohiko Sato Jun Matsuoka Kanichi Kamiya

Year: 1996 Journal: Journal of the Ceramic Society of Japan Vol: 104 (1212)Pages: 777-780 Publisher: Ceramic Society of Japan

DOI: 10.2109/jcersj.104.777

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Abstract

Amorphous Bi2O3-TiO2 and Nb2O5-TiO2 transparent films were successfully prepared by dip coating method, using Bi-Ti complex alkoxide and corresponding metal alkoxide solutions, respectively. The films were amorphous up to 300 or 500°C and highly transparent from 500 to 2000nm. The χ(3) values obtained were mostly in the order of 10-12 esu although the films had high porosity, and the values of 10-11 esu were expected for fully dense amorphous films.

Keywords:

Amorphous solid Alkoxide Materials science Sol-gel Thin film Chemical engineering Mineralogy Nanotechnology Crystallography Chemistry Catalysis Organic chemistry

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Nonlinear Optical Materials Studies

Physical Sciences → Engineering → Biomedical Engineering

Phase-change materials and chalcogenides

Physical Sciences → Materials Science → Materials Chemistry

Glass properties and applications

Physical Sciences → Materials Science → Ceramics and Composites

Sol-Gel Preparation and Third-Order Optical Nonlinearity of Amorphous Bi<sub>2</sub>O<sub>3</sub>-TiO<sub>2</sub> and Nb<sub>2</sub>O<sub>5</sub>-TiO<sub>2</sub> Films

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