JOURNAL ARTICLE

Ultrathin Porous NiCo2O4Nanosheet Arrays on Flexible Carbon Fabric for High-Performance Supercapacitors

Jun DuGang ZhouHaiming ZhangChao ChengJianmin MaWeifeng WeiLibao ChenTaihong Wang

Year: 2013 Journal:   ACS Applied Materials & Interfaces Vol: 5 (15)Pages: 7405-7409   Publisher: American Chemical Society

Abstract

NiCo2O4 with higher specific capacitance is an excellent pseudocapacitive material. However, the bulk NiCo2O4 material prevents the achievement of high energy desity and great rate performance due to the limited electroactive surface area. In this work, NiCo2O4 nanosheet arrays were deposited on flexible carbon fabric (CF) as a high-performance electrode for supercapacitors. The NiCo2O4 arrays were constructed by interconnected ultrathin nanosheets (10 nm) with many interparticle pores. The porous feature of NiCo2O4 nanosheets increases the amount of electroactive sites and facilitates the electrolyte penetration. Hence, the NiCo2O4/CF composites exhibited a high specific capacitance of 2658 F g(-1) (2 A g(-1)), good rate performance, and superior cycling life, suggesting the NiCo2O4/CF is a promising electrode material for flexible electrochemical capacitors.

Keywords:
Materials science Supercapacitor Nanosheet Capacitance Electrode Electrolyte Capacitor Nanotechnology Horizontal scan rate Electrochemistry Carbon fibers Porosity Chemical engineering Composite material Cyclic voltammetry Voltage Composite number Electrical engineering

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267
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30
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0.99
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Citation History

Topics

Supercapacitor Materials and Fabrication
Physical Sciences →  Materials Science →  Electronic, Optical and Magnetic Materials
Advancements in Battery Materials
Physical Sciences →  Engineering →  Electrical and Electronic Engineering
Advanced battery technologies research
Physical Sciences →  Engineering →  Electrical and Electronic Engineering
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