Observation of Hysteretic Bistability in [CoIIICp2]+[FeIIII4]-

J.M. Migliori; William M. Reiff; Atta M. Arif; Joel S. Miller

doi:10.1021/ic049000g

ScienceGate Book Chapters

JOURNAL ARTICLE

Observation of Hysteretic Bistability in [Co^IIICp₂]⁺[Fe^IIII₄]^-

J.M. Migliori William M. Reiff Atta M. Arif Joel S. Miller

Year: 2004 Journal: Inorganic Chemistry Vol: 43 (22)Pages: 6875-6877 Publisher: American Chemical Society

DOI: 10.1021/ic049000g

Get Full-Text PDF Get Analytical Report

Abstract

[Co(III)Cp(2)](+)[Fe(III)I(4)](-) (Cp = cyclopentadienyl) prepared by the double oxidation of FeI(2) and CoCp(2) with iodine exhibits a 30 degrees C thermal hysteresis in magnetic susceptibility between 134 and 164 K that is attributed to a phase transition to a disordered triclinic unit cell from an ordered monoclinic unit cell upon cooling.

Keywords:

Chemistry Bistability Atomic physics Analytical Chemistry (journal) Crystallography Nuclear physics Physics

Metrics

Cited By

1.25

FWCI (Field Weighted Citation Impact)

Refs

0.79

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Citation History

Topics

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Lanthanide and Transition Metal Complexes

Physical Sciences → Materials Science → Materials Chemistry

Organic and Molecular Conductors Research

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Observation of Hysteretic Bistability in [Co^IIICp₂]⁺[Fe^IIII₄]^-

Abstract

Metrics

Citation History

Topics

Related Documents

Tetranuclear {Co^II₂Co^III₂}, Octanuclear {Co^II₄Co^III₄}, and Hexanuclear {Co^III₃Dy^III₃} Pivalate Clusters: Synthesis, Magnetic Characterization, and Theoretical Modeling

Single-Molecule-Magnet Fe^II₄Fe^III₂ and Antiferromagnetic Fe^III₄ Coordination Clusters

Arsenic(III)-Capped 12-Tungsto-2-Arsenates(III) [M₂(As^IIIW₆O₂₅)₂(As^IIIOH)_x]ⁿ⁻ (M = Cr^III, Fe^III, Sc^III, In^III, Ti^IV, Mn^II) and Their Magnetic Properties

Structure of the Chromium(III) Salt [Cp^₂Cr]⁺[Cp^CrCl₃]⁻

Co^II₄, Co^II₇, and a Series of Co^II₂Ln^III (Ln^III = Nd^III, Sm^III, Gd^III, Tb^III, Dy^III) Coordination Clusters: Search for Single Molecule Magnets

Observation of Hysteretic Bistability in [CoIIICp2]+[FeIIII4]-

Abstract

Metrics

Citation History

Topics

Related Documents

Tetranuclear {CoII2CoIII2}, Octanuclear {CoII4CoIII4}, and Hexanuclear {CoIII3DyIII3} Pivalate Clusters: Synthesis, Magnetic Characterization, and Theoretical Modeling

Single-Molecule-Magnet FeII4FeIII2 and Antiferromagnetic FeIII4 Coordination Clusters

Arsenic(III)-Capped 12-Tungsto-2-Arsenates(III) [M2(AsIIIW6O25)2(AsIIIOH)x]n− (M = CrIII, FeIII, ScIII, InIII, TiIV, MnII) and Their Magnetic Properties

Structure of the Chromium(III) Salt [Cp*2Cr]+[Cp*CrCl3]−

CoII4, CoII7, and a Series of CoII2LnIII (LnIII = NdIII, SmIII, GdIII, TbIII, DyIII) Coordination Clusters: Search for Single Molecule Magnets

Observation of Hysteretic Bistability in [Co^IIICp₂]⁺[Fe^IIII₄]^-

Tetranuclear {Co^II₂Co^III₂}, Octanuclear {Co^II₄Co^III₄}, and Hexanuclear {Co^III₃Dy^III₃} Pivalate Clusters: Synthesis, Magnetic Characterization, and Theoretical Modeling

Single-Molecule-Magnet Fe^II₄Fe^III₂ and Antiferromagnetic Fe^III₄ Coordination Clusters

Arsenic(III)-Capped 12-Tungsto-2-Arsenates(III) [M₂(As^IIIW₆O₂₅)₂(As^IIIOH)_x]ⁿ⁻ (M = Cr^III, Fe^III, Sc^III, In^III, Ti^IV, Mn^II) and Their Magnetic Properties

Structure of the Chromium(III) Salt [Cp^₂Cr]⁺[Cp^CrCl₃]⁻

Co^II₄, Co^II₇, and a Series of Co^II₂Ln^III (Ln^III = Nd^III, Sm^III, Gd^III, Tb^III, Dy^III) Coordination Clusters: Search for Single Molecule Magnets