ChemInform Abstract: ORTHO‐METALATED TRIPHENYLPHOSPH

David J. Cole‐Hamilton; G. Wilkinson

doi:10.1002/chin.197729331

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ChemInform Abstract: ORTHO‐METALATED TRIPHENYLPHOSPH

David J. Cole‐Hamilton G. Wilkinson

Year: 1977 Journal: Chemischer Informationsdienst Vol: 8 (29) Publisher: Wiley

DOI: 10.1002/chin.197729331

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Abstract

Abstract Der Chlorohydrido‐Ru(II)‐ Komplex (I) bildet mit Trimethylsilylmethyl‐Li und Methyl‐Li in Äther oder THF die instabilen, äußerst reaktionsfähigen Hydridoalkyl‐Komplexe (II), die sich bei Raumtemperatur rasch einer ortho‐Metallierung unter Freisetzen von Tetramethylsilan bzw.Methan und Bildung der Produkte (III) unterwerfen.

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Medicinal chemistry Chemistry

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Coordination Chemistry and Organometallics

Physical Sciences → Chemistry → Organic Chemistry

Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

ChemInform Abstract: ORTHO‐METALATED TRIPHENYLPHOSPH

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