Electrochemical Lithium Intercalation in Monoclinic Nb<sub>12</sub>O<sub>29</sub>

Yan Li; Chunwen Sun; John B. Goodenough

doi:10.1021/cm200334a

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Electrochemical Lithium Intercalation in Monoclinic Nb₁₂O₂₉

Yan Li Chunwen Sun John B. Goodenough

Year: 2011 Journal: Chemistry of Materials Vol: 23 (9)Pages: 2292-2294 Publisher: American Chemical Society

DOI: 10.1021/cm200334a

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Abstract

Monoclinic Nb12O29 with Wadsley shear structure shows interstitial sites for Li intercalation/extraction reversibly in the voltage windows of 2.5−1.0 V. In spite of its metallic characteristic, samples with carbon coating show an improved rate capability.

Keywords:

Monoclinic crystal system Intercalation (chemistry) Materials science Electrochemistry Lithium (medication) Crystallography Metal Lithium metal Inorganic chemistry Crystal structure Anode Electrode Metallurgy Physical chemistry Chemistry

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Electrochemical Lithium Intercalation in Monoclinic Nb₁₂O₂₉

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