Analysis of Thermal Aging and Structural Stability of Li[Li_x(Ni_0.3Co_0.1Mn_0.6)_1-x]O₂ (x = 0.11) Cathode Active Material for Rechargeable Li-Ion Batteries

Abstract

The high rate capability of Mn-rich Li[Li x (Ni 0.3 Co 0.1 Mn 0.6 ) 1- x ]O 2 ( x = 0.11) cathode active materials is investigated by cycling the cell at a given rate for five cycles and keeping the cell idle under thermal control chamber for 10 h and the same process repeating up to 30 cycles. The before and after thermal aging of Mn-rich cathode materials deliver the initial discharge capacity of 153 and 157.32 mA h g -1 up to 30 cycles and also it is maintained the average specific discharge capacity of 140 mA h g -1 for before thermal aging and more than 90% capacity retention. After thermal aging of cathode materials have maintain the average specific discharge capacity of 155 mA h g -1 and more than 97% capacity retentions. During charging, they are not oxidized further; Ni 2+ and at least part of Co 3+ ions are oxidized to higher valence states. During the discharge reactions, the small amount of Mn 3+ reduced to the Mn 4+ and some part of Ni 3+ ions are reduced to Ni 4+ . Also the Co 3+ ions are fully reduced to the Co 4+ state, which due to thermal aging studies does not have major affects in the Mn-rich layered structure under thermal control chamber. These thermal aging analyses are essential to achieve a deeper understanding of the structural defects and safety views for Li-ion batteries to use in electric vehicle technologies.