JOURNAL ARTICLE

[1,2-Bis(diphenylphosphino)ethane]chlorido(η5-pentamethylcyclopentadienyl)iron(II) dichloromethane solvate

Ya‐Ping OuDan FengJingjing Yuan

Year: 2010 Journal:   Acta Crystallographica Section E Structure Reports Online Vol: 66 (8)Pages: m921-m921   Publisher: International Union of Crystallography

Abstract

In the title compound, [Fe(C(10)H(15))Cl(C(26)H(24)P(2))]·CH(2)Cl(2), the Fe(II) atom is coordinated by two P atoms from a 1,2-bis-(diphenyl-phosphino)ethane ligand [Fe-P = 2.2130 (7) and 2.2231 (7) Å], a chloride anion [Fe-Cl = 2.3329 (7) Å] and a penta-methyl-cyclo-penta-dienyl (Cp*) ligand [Fe-centroid(Cp*) = 1.732 (3) Å] in a typical piano-stool geometry. In the crystal structure, the complex and solvent mol-ecules are paired via weak C-H⋯Cl inter-actions.

Keywords:
Dichloromethane Chemistry Medicinal chemistry Organic chemistry Solvent

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Citation History

Topics

Metal complexes synthesis and properties
Health Sciences →  Medicine →  Oncology
Crystal structures of chemical compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry
Metal-Catalyzed Oxygenation Mechanisms
Physical Sciences →  Chemistry →  Inorganic Chemistry

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