Synthesis and Upconversion Luminescence of YF₃:Yb³⁺,Tm³⁺ and TiO₂-Coated YF₃:Yb³⁺,Tm³⁺ Microcrystals

Abstract

YF3:Yb3+, Tm3+ microcrystals were prepared by a microemulsion method. The microcrystals were coated with TiO2 by hydrolysis of titanium n-butoxide (TBOT). Transform electron microscopy and X-ray diffraction were used to characterize the core/shell materials. The results indicated that the low TBOT/YF3 molar ratio was favorable to preparing the uniform TiO2 coatings. The upconversion luminescence properties of YF3:Yb3+, Tm3+ and TiO2-coated YF3:Yb3+, Tm3+ microcrystals were studied under 980-nm excitation. The 1I6 --> 3H6, 1I6 --> 3F4, 1D2 --> 3H6, 1D2 --> 3F4, 1G4 --> 3H6, and 1G4 --> 3F4 emissions were observed. The upconversion mechanisms were discussed in detail.