JOURNAL ARTICLE

Electrochemical Performance of Al<sub>2</sub>O<sub>3</sub>-Coated LiNi<sub>1/3</sub>Co<sub>1/3</sub>Mn<sub>1/3</sub>O<sub>2</sub> Cathode Materials for Li-Ion Batteries

Jian Gang LiXiangming HeRu ZhaoChun Rong WanShi Chao Zhang

Year: 2007 Journal:   Key engineering materials Vol: 336-338 Pages: 459-462   Publisher: Trans Tech Publications

Abstract

Al2O3-coated LiNi1/3Co1/3Mn1/3O2 powders with excellent electrochemical performance have been synthesized. The electrochemical performance of Al2O3-coated LiNi1/3Co1/3Mn1/3O2 electrodes has been studied as function of the level of Al2O3 coating. Coated LiNi1/3Co1/3Mn1/3O2 samples shows higher discharge capacity and better capacity retention than the base one. Among the coated samples, 1.0mol% coated sample exhibits the best electrical performance. It presents an initial discharge capacity of 174.5 mAh g-1 over 2.5~4.4V, and 84.7% capacity retention after 30 cycles over 2.5~4.6V.

Keywords:
Electrochemistry Materials science Coating Electrode Base (topology) Analytical Chemistry (journal) Chemical engineering Metallurgy Nanotechnology Chemistry Chromatography Mathematics Physical chemistry

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Topics

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