Langbeinite-type mixed-valence (NH4)(H3O)TiIIITiIV(PO4)3
Yunlong FuZhiwei XuJia-Lin RenSeik Weng Ng
Abstract
The anionic component of the langbeinite-type title compound, ammonium oxonium dititanium(III,IV) tris(phosphate), is an infinite three-dimensional [Ti2(PO4)3]2− network based on PO4 tetrahedra corner-linked to TiO6 octahedra; the charge-balancing ammonium and oxonium cations occupy the cavities in the network and interact by way of N—H⋯O and O—H⋯O hydrogen bonds. The two independent Ti atoms, the ammonium N atom and the oxonium O atom lie on special positions of site symmetry 3.
Metrics
Citation History
Topics
Related Documents
Ein gemischtvalentes Oxometallat mit Cr3+ anstelle von Ti3+: Ba2Ti4 4+Cr2O13 / A Mixed Valent Oxometallate with Cr3+ Instead of Ti3+ Ba2Ti4 4+ Cr2O13
K2FeIII 0.5TiIII 0.5TiIV 1.0(PO4)3: Preparation and Characterization of a Langbeinite-related Phosphate Containing Iron(III) and Mixed-valent Titanium
Ivan V. OgorodnykІgor V. ZatovskyВ.Н. БаумерNikolay S. SlobodyanikОлег В. ШишкинI. P. Vorona
Contribution á l'étude du système quinaire Ca++NH4+H+NO3−PO4−−−H2O. II. Les systèmes ternaires limites Ca++H+NO3H2O, NH4+H+NO3−H2O ct Ca++NH4+NO3−H2O à 25°
Alcaparrosaite, K3Ti4+Fe3+(SO4)4O(H2O)2, a new hydrophobic Ti4+ sulfate from Alcaparrosa, Chile
A. R. KampfStuart J. MillsR. M. HousleyPeter A. WilliamsM. Dini
ChemInform Abstract: K2FeIII0.5TiIII0.5 TiIV1.0(PO4)3: Preparation and Characterization of a Langbeinite‐Related Phosphate Containing Iron(III) and Mixed‐Valent Titanium
Ivan V. OgorodnykІgor V. ZatovskyВ.Н. БаумерNikolay S. SlobodyanikОлег В. ШишкинI. P. Vorona