JOURNAL ARTICLE
H2N(CH2)2NH3+.[Mn{H2N(CH2)2NH2}3]2+.[Sb Se4]3−
Frank WendlandChristian NätherM. SchurWolfgang Bensch
Year: 1998 Journal: Acta Crystallographica Section C Crystal Structure Communications Vol: 54 (3)Pages: 317-319 Publisher: Wiley
Abstract
The reaction of elemental manganese, antimony and selenium with 1,2-ethanediamine (en) in an aqueous ethaneamine solution under hydrothermal conditions yields orange crystals of 2-aminoethylammonium tris(1,2-ethanediamine)manganese tetraselenoantimonate, enH. Mn(en)3.SbSe4. The structure contains tetrahedral SbSe43−anions, octahedral Mn(en)32+ cations as well as monoprotonated ethanediamine molecules.
Keywords:
Octahedron Manganese Antimony Chemistry Aqueous solution Inorganic chemistry Selenium Crystallography Crystal structure Physical chemistry
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Topics
Crystal Structures and Properties
Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials
Chemical Thermodynamics and Molecular Structure
Physical Sciences → Chemistry → Organic Chemistry
Crystallography and molecular interactions
Physical Sciences → Chemistry → Physical and Theoretical Chemistry
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