JOURNAL ARTICLE

NHC carbene supported half-sandwich hydridosilyl complexes of ruthenium: the impact of supporting ligands on Si⋯H interligand interactions

Abstract

Electron donating NHC carbene ligand IPr exerts stronger RuH⋯Si interactions in complexes Cp(IPr)RuH2(SiR3) than in related iPr3P complexes Cp(iPr3P)RuH2(SiR3).

Keywords:
Carbene Ruthenium Chemistry Polymer chemistry Stereochemistry Medicinal chemistry Catalysis Organic chemistry

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63
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0.84
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Citation History

Topics

N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
Physical Sciences →  Chemistry →  Organic Chemistry
Catalytic Cross-Coupling Reactions
Physical Sciences →  Chemistry →  Organic Chemistry
Organometallic Complex Synthesis and Catalysis
Physical Sciences →  Chemistry →  Organic Chemistry
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