Cationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands

Norio Nakata; Noriko Sekizawa; Akihiko Ishii

doi:10.1039/c5cc03062e

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Cationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands

Norio Nakata Noriko Sekizawa Akihiko Ishii

Year: 2015 Journal: Chemical Communications Vol: 51 (50)Pages: 10111-10114 Publisher: Royal Society of Chemistry

DOI: 10.1039/c5cc03062e

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Abstract

New cationic (μ-hydrido)(μ-germyl) diplatinum and dipalladium complexes, [{M(dcpe)}₂(μ-H)(μ-GeHTrip)]⁺ (M = Pt, Pd), were prepared by hydride-abstraction reactions of [MH(GeH₂Trip)(dcpe)] with B(C₆F₅)₃.

Keywords:

Palladium Cationic polymerization Bridging (networking) Platinum Chemistry Polymer chemistry Organic chemistry Catalysis Computer science

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Catalytic Cross-Coupling Reactions

Physical Sciences → Chemistry → Organic Chemistry

Cationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands

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