JOURNAL ARTICLE
Acid-base catalysis using chiral palladium complexes
Mikiko SodeokaYoshitaka Hamashima
Year: 2006 Journal: Pure and Applied Chemistry Vol: 78 (2)Pages: 477-494 Publisher: International Union of Pure and Applied Chemistry
Abstract
Abstract Chiral Pd aqua and µ-hydroxo complexes were found to act as mild Brønsted acids and bases, and chiral Pd enolates were generated from these complexes even under acidic conditions. Highly enantioselective Michael addition, Mannich-type reaction, fluorination, and conjugate addition of amines have been developed based on the acid-base character of these Pd complexes.
Keywords:
Chemistry Conjugate Enantioselective synthesis Palladium Base (topology) Catalysis Brønsted–Lowry acid–base theory Combinatorial chemistry Organic chemistry
Metrics
40
Cited By
3.41
FWCI (Field Weighted Citation Impact)
11
Refs
0.92
Citation Normalized Percentile
Is in top 1%
Is in top 10%
Citation History
Topics
Asymmetric Hydrogenation and Catalysis
Physical Sciences → Chemistry → Inorganic Chemistry
Chemical Synthesis and Analysis
Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology
Asymmetric Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
Related Documents
JOURNAL ARTICLE
Acid—Base Catalysis Using Chiral Palladium Complexes
Mikiko SodeokaYoshitaka Hamashima
Journal: ChemInform Year: 2006 Vol: 37 (31)
JOURNAL ARTICLE
Acid—Base Catalysis of Chiral Pd Complexes: Development of Novel Asymmetric Reactions
Journal: ChemInform Year: 2006 Vol: 37 (9)
JOURNAL ARTICLE
Accessing Dihydropyrans Under Palladium/Chiral Phosphonic Acid Synergistic Catalysis
Journal: Synfacts Year: 2025 Vol: 21 (07)Pages: 706-706
BOOK-CHAPTER
Catalysis Using Vanadium/Chiral Schiff Base Ligands
Stereoselective Pericyclic Reactions, Cross Coupling, and C—H and C—X Activation Year: 2011 Pages: 1-1
BOOK-CHAPTER
Catalysis Using Titanium/Chiral Schiff Base Ligands
Stereoselective Pericyclic Reactions, Cross Coupling, and C—H and C—X Activation Year: 2011 Pages: 1-1