Post‐Synthetic Modification of Tagged Metal–Organic Frameworks
Andrew D. BurrowsChristopher G. FrostMary F. MahonChristopher Richardson
Abstract
Playing tag with MOFs: Zinc metal–organic frameworks with pendant aldehyde and methoxy groups are prepared. The aldehyde-tagged MOF takes up 2,4-dinitrophenylhydrazine, reacting to form a hydrazone-functionalized MOF which is crystallographically characterized. Use of both aldehyde- and methoxy-functionalized dicarboxylates leads to MOFs containing both ligands, of which the aldehyde groups can be selectively reacted.
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