Highly Porous, Homochiral Metal–Organic Frameworks: Solvent‐Exchange‐Induced Single‐Crystal to Single‐Crystal Transformations

Abstract

Change and change about: Highly porous, homochiral metal–organic frameworks (MOFs) undergo reversible single-crystal to single-crystal and single-crystal to amorphous to single-crystal structural transformations when exposed to solvent vapors or air. These results suggest that true heterogeneous asymmetric catalysts can be built from homochiral MOFs. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z462711_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.