Bio‐based hyperbranched polyurethane/multi‐walled carbon nanotube nanocomposites as shape memory materials

Abstract

Mesua ferrea L. seed oil based hyperbranched polyurethane/multi‐walled carbon nanotube nanocomposites were prepared by solution polymerization technique. The multi‐walled carbon nanotubes were modified with the polyoxyethylene octyl phenyl ether (Triton X‐100). The transmission electron microscopy and Fourier transform infrared spectroscopic study revealed the homogeneous distribution of the multi‐walled carbon nanotubes in the polymer matrix and the presence of strong interfacial interaction between them, respectively. The tensile strength (5.5–21.5 MPa) and scratch resistance (3–6.1 kg) increase with the increase of the content of carbon nanotubes (0 to 2 wt%). The thermo‐gravimetric analysis result showed the increment of thermal stability (240–275°C) of the nanocomposites. All the prepared nanocomposites exhibited the excellent shape fixity and shape recovery. The shape recovery time decreases (127–73 s) with the increase of the concentration of carbon nanotubes in the nanocomposites. Thus the prepared nanocomposites might be utilized as advanced shape memory applications. POLYM. COMPOS., 35:636–643, 2014. © 2013 Society of Plastics Engineers