Selective host–guest interaction of single-walled carbon nanotubes with functionalised fullerenes
David A. BritzAndrei N. KhlobystovJiawei WangAdam O'NeilMartyn PoliakoffArzhang ArdavanG. Andrew D. Briggs
Abstract
Exohedrally functionalised fullerenes have been inserted in single-walled carbon nanotubes (SWNTs) with the aid of supercritical carbon dioxide to form peapods; C(61)(COOEt)(2) are encapsulated in SWNTs in high yield, whereas C(61)(COOH)(2) aggregate via hydrogen bonding to form a supramolecular complex, which sterically hinders encapsulation and causes it to adhere to the exterior surface of the SWNTs.
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