JOURNAL ARTICLE

Nanoscale Light‐Harvesting Metal–Organic Frameworks

Xuanjun ZhangMohamed A. BallemZhangjun HuPeder BergmanKajsa Uvdal

Year: 2011 Journal:   Angewandte Chemie International Edition Vol: 50 (25)Pages: 5729-5733   Publisher: Wiley

Abstract

Highly crystalline nanoparticles of metal–organic frameworks with efficient light-harvesting properties were prepared by coordination-directed assembly (see picture). Functionalization of the ligands with long alkyl chains effectively stabilizes the nanoparticles and increases crystallinity. Different metal ions and ligands are organized into single nanoparticles and both organic acceptors and lanthanide ions can be co-sensitized within the frameworks. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

Keywords:
Nanoparticle Crystallinity Lanthanide Metal-organic framework Nanotechnology Nanoscopic scale Materials science Surface modification Metal ions in aqueous solution Metal Ion Chemistry Chemical engineering Organic chemistry Engineering Metallurgy

Metrics

149
Cited By
8.44
FWCI (Field Weighted Citation Impact)
61
Refs
0.98
Citation Normalized Percentile
Is in top 1%
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Citation History

Topics

Metal-Organic Frameworks: Synthesis and Applications
Physical Sciences →  Chemistry →  Inorganic Chemistry
Magnetism in coordination complexes
Physical Sciences →  Materials Science →  Electronic, Optical and Magnetic Materials
Lanthanide and Transition Metal Complexes
Physical Sciences →  Materials Science →  Materials Chemistry

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