Thiolatoverbrückte Ni‐Fe‐Komplexe mit Fe<sup>0</sup>‐ und Fe<sup>II</sup>‐CO‐Komplexfragmenten

Chia‐Huei Lai; Joseph H. Reibenspies; Marcetta Y. Darensbourg

doi:10.1002/ange.19961082031

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Thiolatoverbrückte Ni‐Fe‐Komplexe mit Fe⁰‐ und Fe^II‐CO‐Komplexfragmenten

Chia‐Huei Lai Joseph H. Reibenspies Marcetta Y. Darensbourg

Year: 1996 Journal: Angewandte Chemie Vol: 108 (20)Pages: 2551-2554 Publisher: Wiley

DOI: 10.1002/ange.19961082031

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Abstract

Sehr stabil und ineinander überführbar sind die Ni‐Fe‐Verbindungen 1 und 2 , in denen die cis ‐Dithiolato‐Schwefelatome an Fe 0 ‐CO‐ bzw. Fe II ‐CO‐Komplexfragmente binden. Anders als die Ni‐S‐Abstände, die nahezu unabhängig von der Oxidationsstufe der Eisenzentren und von der Zähnigkeit des Metallothiolatoliganden sind, unterscheiden sich die Ni‐Fe‐Abstände in beiden Verbindungen um 0.7 Å. magnified image

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Metalloenzymes and iron-sulfur proteins

Physical Sciences → Energy → Renewable Energy, Sustainability and the Environment

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Metal complexes synthesis and properties

Health Sciences → Medicine → Oncology

Thiolatoverbrückte Ni‐Fe‐Komplexe mit Fe⁰‐ und Fe^II‐CO‐Komplexfragmenten

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