Carbon Dioxide Hydrogenation to Formic Acid by Using a Heterogeneous Gold Catalyst

Delia Preti; Claudio Resta; Sergio Squarcialupi; Giuseppe Fachinetti

doi:10.1002/anie.201105481

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Carbon Dioxide Hydrogenation to Formic Acid by Using a Heterogeneous Gold Catalyst

Delia Preti Claudio Resta Sergio Squarcialupi Giuseppe Fachinetti

Year: 2011 Journal: Angewandte Chemie International Edition Vol: 50 (52)Pages: 12551-12554 Publisher: Wiley

DOI: 10.1002/anie.201105481

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Abstract

AUROlite, consisting of gold supported on titania (picture shows extrudates in a steel net cage), is a robust catalyst for the production of catalyst-free HCOOH/NEt(3) adducts from H(2), CO(2), and neat NEt(3). Pure HCOOH is freed from the adducts by amine exchange.

Keywords:

Formic acid Catalysis Carbon dioxide Chemistry Electrochemical reduction of carbon dioxide Inorganic chemistry Chemical engineering Materials science Organic chemistry Carbon monoxide

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Carbon dioxide utilization in catalysis

Physical Sciences → Chemical Engineering → Process Chemistry and Technology

Catalysts for Methane Reforming

Physical Sciences → Chemical Engineering → Catalysis

CO2 Reduction Techniques and Catalysts

Physical Sciences → Energy → Renewable Energy, Sustainability and the Environment

Carbon Dioxide Hydrogenation to Formic Acid by Using a Heterogeneous Gold Catalyst

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