Synthesis of Enantiomerically Pure 1,2-Disubstituted 2-Selenoamines
Esther TorrenteGarcia LuisA. M. Martín-CastroAlessandro Degl’InnocentiAntonella CapperucciLucrezia Frateschi
Abstract
Optically pure phenylseleno-(S)-2-p-tolylsulfinylbenzylcarbanions react with (S)-N-2-p-tolylsulfinylimines derived from aliphatic and aromatic aldehydes in a highly stereoselective manner affording bis-sulfinylselenoamines, easily transformed into 1-phenyl, 2-aryl (or alkyl)-2-phenylseleno ethylamines by subsequent reactions, which were treatment reactions with t-BuLi and TFA
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