JOURNAL ARTICLE

L-Aspartic acid nitrate–L-aspartic acid (1/1)

B. SridharN. SrinivasanR. Rajaram

Year: 2002 Journal:   Acta Crystallographica Section E Structure Reports Online Vol: 58 (12)Pages: o1372-o1374   Publisher: International Union of Crystallography

Abstract

In the title compound, C4H8NO4+·C4H7NO4·NO3−, the cation and neutral mol­ecule are connected by an asymmetric hydrogen bond. The cation, residue 1, exists in a gauche I conformation, whereas the neutral mol­ecule, residue 2, exhibits a gauche II conformation. A syn–syn orientation is also observed in this structure and residue 1 is involved in a straight (S1) head-to-tail sequence. The structure is stabilized by both inter- and intramolecular N—H⋯O hydrogen bonding.

Keywords:
Residue (chemistry) Aspartic acid Hydrogen bond Intramolecular force Chemistry Stereochemistry Amino acid residue Crystallography Peptide sequence Amino acid Biochemistry Molecule Organic chemistry

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Citation History

Topics

Crystal structures of chemical compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry
Crystallography and molecular interactions
Physical Sciences →  Chemistry →  Physical and Theoretical Chemistry
Chemical Synthesis and Analysis
Life Sciences →  Biochemistry, Genetics and Molecular Biology →  Molecular Biology

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