Synthesis of a layered zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn2(PO4)(HPO4)2]·H2O, and its transformation to a extra-large pore three-dimensional zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn3(PO4)(HPO4)3]

Srinivasan Natarajan

doi:10.1039/b200293k

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Synthesis of a layered zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn2(PO4)(HPO4)2]·H2O, and its transformation to a extra-large pore three-dimensional zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn3(PO4)(HPO4)3]

Srinivasan Natarajan

Year: 2002 Journal: Chemical Communications Pages: 780-781 Publisher: Royal Society of Chemistry

DOI: 10.1039/b200293k

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Abstract

An unusual two-dimensional zinc phosphate with pendant phosphate groups, projecting into the inter-lamellar space between the layers, has been synthesized and is shown to transform into a three-dimensional structure with 16-membered bifurcated channels, giving evidence for the building up process in the formation of open-framework structures.

Keywords:

Zinc phosphate Zinc Lamellar structure Phosphate Materials science Chemistry Transformation (genetics) Crystallography Characterisation of pore space in soil Chemical engineering Inorganic chemistry Organic chemistry Porosity

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Chemical Synthesis and Characterization

Physical Sciences → Environmental Science → Industrial and Manufacturing Engineering

Zeolite Catalysis and Synthesis

Physical Sciences → Chemistry → Inorganic Chemistry

Crystal Structures and Properties

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Synthesis of a layered zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn2(PO4)(HPO4)2]·H2O, and its transformation to a extra-large pore three-dimensional zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn3(PO4)(HPO4)3]

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