JOURNAL ARTICLE

Chromium(III), Iron(III) and Cobalt(III) Complexes of N, N'- Ethylenebis(ο-hydroxyphenylglycine)

杉浦 公昭山崎 一雄

Year: 1968 Journal:   Nippon kagaku zassi Vol: 89 (9)Pages: 853-855   Publisher: Chemical Society of Japan

Abstract

N,N'-エチレンピス(ο-オキシフェニルグリシン)を配位子とする3価金属の新しい錯体, K[Cr(ehpg)], K[Fe(ehpg)], K[Co(ehpg)] の3種を合成し, その磁性ならびに可視, 紫外および赤外吸収スペクトルなどを測定した。各錯体の色と磁気モーメント(室温)はクロム: 紫色, 3.8 Bohr magneton, 鉄: 赤褐色, 5.7 Bohr magneton, コバルト:黒褐色, 反磁性である。これらはすべてこの配位子が六座としズ配位した正八面体型構造をとっているものと推定される。

Keywords:
Chromium Cobalt Chemistry Metallurgy Inorganic chemistry Materials science

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Topics

Metal complexes synthesis and properties
Health Sciences →  Medicine →  Oncology
Photochemistry and Electron Transfer Studies
Physical Sciences →  Chemistry →  Physical and Theoretical Chemistry
Magnetism in coordination complexes
Physical Sciences →  Materials Science →  Electronic, Optical and Magnetic Materials

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