Assembling Ellipsoidal Particles at Fluid Interfaces Using Switchable Dipolar Capillary Interactions

Abstract

How to dynamically tune an assembly of anisotropic colloidal particles adsorbed at fluid-fluid interfaces using dipolar capillary interactions is demonstrated. A previously discovered first-order phase transition is exploited and it is shown how to spontaneously turn off these dipolar capillary interactions by exceeding a critical field strength, providing unprecedented control of the bottom-up fabrication of soft materials.