Translucent α‐Sialon Ceramics by Hot Pressing

Abstract

The single‐phase α‐sialon ceramics with high optical transmittance have been prepared by hot pressing. The maximum transmittance reached 65.2% and 52.2% in the infrared wavelength region, 58.5% and 40% in the visible region for the samples 1.0 and 1.5 mm thickness, respectively. The material also exhibited good mechanical properties of high hardness (20 GPa) and better fracture toughness (5.1 MPa·m 1/2 ). Both high optical transmittance and improved toughness of α‐sialon ceramics were attributed to the less‐grain‐boundary glassy phase and the homogeneous microstructure, which was obtained by a proper process and confirmed by SEM and TEM observation, compared to that prepared by ordinary sintering. It is, therefore, expected that the translucent α‐sialon ceramics could be a promising optical window material.