Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies

Miguel Rubio; Maxime A. Siegler; Anthony L. Spek; Joost N. H. Reek

doi:10.1039/c003352a

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Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies

Miguel Rubio Maxime A. Siegler Anthony L. Spek Joost N. H. Reek

Year: 2010 Journal: Dalton Transactions Vol: 39 (23)Pages: 5432-5432 Publisher: Royal Society of Chemistry

DOI: 10.1039/c003352a

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Abstract

New coordination polymers based on different combinations of silver atoms and pyridyl-substituted N-heterocyclic carbene moieties are described. The addition of Zn(ii) templates leads to Ag-Zn supramolecular assemblies via selective ZnN interactions; a process that can be reverted.

Keywords:

Supramolecular chemistry Polymer Materials science Chemistry Polymer chemistry Nanotechnology Crystallography Crystal structure Composite material

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N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Physical Sciences → Chemistry → Organic Chemistry

Catalytic Cross-Coupling Reactions

Physical Sciences → Chemistry → Organic Chemistry

Carbon dioxide utilization in catalysis

Physical Sciences → Chemical Engineering → Process Chemistry and Technology

Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies

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